The mathematical description for the electropolymerization of furan, pyrrole and thiophene derivatives in alkaline media

Authors

  • Volodymyr Tkach Chernivtsi National University, Ukraine
  • Vasyl´ Nechyporuk Chernivtsi National University, Ukraine
  • Petro Yagodynets´ Chernivtsi National University, Ukraine

Abstract

The electropolymerization of furan, pyrrole and thiophene in strong basic media was mathematically described. Two models for the cases of the insoluble and soluble anodes were described and analyzed by using the linear stability theory and bifurcation analysis and compared with the models for other cases of electropolymerization. The causes for the oscillatory behavior, monotonic instabilities and steady-state stability conditions were found. 

References

- T. Yamamoto, Asia Materials2, 2010, 54.

- .J. Mostany, B.R Scharifker. Electrochim. Acta, 1997, 42, 291.

- J. Mostany, B.R Scharifker. Synth.Met., 1997, 87, 179.

- S. Kumar.: E-J. Chem, 2010, 8, , 846.

- Sharma L K, Kumar S, Singh S and Singh R K P, Russ.J.Electrochem, 2010, 46, , 37.

- Sadki S. Scottland Ph., Brodie N., Saboraud G, Chem. Soc. Rev, 2000, 29, 283.

- N. Bodnaryuk-Lupshak, O.I. Aksimentyeva, Vopr. Khim.Khim.Techn., 1998, 50, 1, published in Ukrainian

- V.M. Nalwa. Handbook of Advanced Electronic and Photonic Materials and Devices, V8, Conducting polymers, Wiley &Sons Ltd.- 1997.

- J. Roncali.: Chem. Rev, 1992, 92, 711.

- I.Das, N.R.Agrawal, S.A.Ansari, S.K.Gupta,Ind. J. Chem, 2008, 47°, 1798.

- S.U. Rahman, M.S. Ba-Shammakh, Synth. Met., 2004, 140, 207.

- A.S.Liu, M.A.S. Oliveira. J. Braz. Chem Soc., 2007, 18, 143.

- Sazou D., Synth. Met., 2002, 130, 45.

- I.Das, N. Goel, N.R. Agrawal, S. K. Gupta, , J. Phys. Chem, 2010, 114, 12888.

- M. Bazzaoui, E.A. Bazzaoui, L. Martins, J.I. Martins, Synth. Met., 2002, 130, 73.

- I.Das, N. Goel, S. K. Gupta, N.R. Agrawal, J. Electroanal. Chem,2012. 670.

- M. Iseki, Y. Sugiyama, US Patent US5608358 A, 1997, Sanyo Electric Co., Ltd. http://www.google.com/patents/US5608358.

- Das, N.R. Agrawal, S.K.Gupta, R.P.Rastogi, J. Phys. Chem, 2009, 113, 5296.

- T. Tatsuma, T. Ogawa, R. Sato, N. Oyama, J. Electroanal. Chem, 2001, 501, 180

- K.Aoki, I. Mukoyama, J.Chen, Russ.J. Electrochem, 2004, 40, 319.

- L. Hudson, M.R. Bassett, Rev. Chem. Eng, 1991, 7, 108.

- M. Pagitsas, S. Dimitra, Electrochimica Acta, 1991, 36, 1301.

- A.J. Pearlstein, J.A. Johnson, J. Electrochem. Soc, 1989, 136, 1290.

- V.Tkach, V. Nechyporuk, P. Yagodynets, Ciên. Tecn. Mat, 2012, 24, 54.

- V.Tkach, V. Nechyporuk, P. Yagodynets, Afinidad, 2013, 70, 73.

- V.Tkach, V. Nechyporuk, P. Yagodynets, Avances en Química, 2013, 8, 9.

- V. Tkach, V. Nechyporuk, P. Yagodynets’, Tecn. Met. Mat. Min, 2013, 10, 249.

- V. V. Tkach, V. V. Nechyporuk, P. I. Yagodynets´, Geor. Chem. J., 2011, 11, 387.

- V.V. Tkach, V.V. Nechyporuk, P.I. Yagodynets’, S.C. de Oliveira, Al. M. Da Rocha, J. Sib. Fed. Univ. Chemistry., 2014, 7, 403, published in Russian.

- V. V.Tkach, V. V.Nechyporuk, P. I. Yagodynets´, Proceeding of the 3rdPortuguese Young Chemists’ Meeting, Porto, Portugal, 2012, 176, http://gqj.spq.pt/3pychem/images/Book_Abstracts_3PYCheM.pdf.

- V. V. Tkach, V. V. Nechyporuk, P. I. Yagodynets´, XXVI Congreso Peruano de Química Mariano Eduardo de Rivero y Ustáriz, Arequipa, Perú, 2012. 137.

- V.V Tkach, V.V Nechyporuk., 4thInternational Symposium on Flexible Organic Electronics, Thessaloniki, 10thof July –14th of July, 2011, 148 .

- V.V. Tkach, V.V. Nechyporuk, O.T. Slipenyuk, Ecl. Quím., 2012, 37, 72.

- V.V. Tkach, V.V. Nechyporuk, Ecl. Quím., 2012, 37, 68.

- Y.Jung, N. Singh, K.-Sh. Choi, Angew. Chem. Int. Ed., 2009, 48, 8331.

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Published

2015-01-12

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Section

Electrochemistry