Direct use of mineral fertilizers MAP, DAP, and TSP as heterogeneous catalysts in organic reactions

Authors

  • Imane Bahammou Laboratory of Organic, Organometallic and Theoretical Chemistry, University of IbnTofail, B.P. 133, Kenitra, Morocco
  • Ayoub Esaady Laboratory of Organic, Organometallic and Theoretical Chemistry, University of IbnTofail, B.P. 133, Kenitra, Morocco
  • Said Boukhris Laboratory of Organic, Organometallic and Theoretical Chemistry, University of IbnTofail, B.P. 133, Kenitra, Morocco
  • Rachida Ghailane Laboratory of Organic, Organometallic and Theoretical Chemistry, University of IbnTofail, B.P. 133, Kenitra, Morocco
  • Nouzha Habbadi Laboratory of Organic, Organometallic and Theoretical Chemistry, University of IbnTofail, B.P. 133, Kenitra, Morocco
  • Amina Hassikou Laboratory of Organic, Organometallic and Theoretical Chemistry, University of IbnTofail, B.P. 133, Kenitra, Morocco
  • Abdelaziz Souizi Laboratory of Organic, Organometallic and Theoretical Chemistry, University of IbnTofail, B.P. 133, Kenitra, Morocco

DOI:

https://doi.org/10.13171/mjc56/01607062219-souizi

Abstract

In this paper, we reported the first use of phosphate fertilizers (MAP, DAP, and TSP) as heterogeneous catalysts for organic reactions.  Their catalytic activities were investigated in the first time in Knoevenagel condensation of various aromatic aldehydes with malononitrile at room temperature.  These minerals phosphate showed high catalytic activities and ability to be recovering and reusing without a significant loss in their catalytic activities.  In order to reach the optimal reaction conditions for Knoevenagel condensation, we carried out a kinetic study of the effect of reaction time, the effect of solvent, the amount of catalysts and the variation of the range of the particles size the more active.  The best conditions were obtained by the use of these fertilizers (MAP, DAP, and TSP) in their commercial status, simply crashed in powder, without any purification, using ethanol as solvent.  These phosphate fertilizers prove to be very promising and effective heterogeneous catalysts for the condensation of Knoevenagel.

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Published

2016-07-06

Issue

Vol. 5 No. 6 (2016)

Section

Catalysis Chemistry

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