Hydrothermal synthesis and crystal structure of a new coordination polymer: [Zn1(deta)(btec)(H2O)2]n

Authors

  • Manel Halouani Laboratoire de Chimie Inorganique, Université de Sfax, Faculté des Sciences de Sfax, BP 1171, 3000 Sfax, Tunisia.
  • Mohamed Abdelhedi Laboratoire de Chimie Inorganique, Université de Sfax, Faculté des Sciences de Sfax, BP 1171, 3000 Sfax, Tunisia.
  • Mohamed Dammak Laboratoire de Chimie Inorganique, Université de Sfax, Faculté des Sciences de Sfax, BP 1171, 3000 Sfax, Tunisia.
  • Nathalie Audebrand Laboratoire de Matériaux Inorganiques: Chimie Douce et Réactivité, UMR 6226 Sciences Chimiques de Rennes, Université Rennes 1, France
  • Lilia Ktari Laboratoire de Chimie Inorganique, Université de Sfax, Faculté des Sciences de Sfax, BP 1171, 3000 Sfax, Tunisia.

DOI:

https://doi.org/10.13171/mjc.2.4.2013.03.05.10

Abstract

A new metal–organic compound [Zn1(deta)(btec)(H2O)2]n where (deta= Diethylenetriamine) and (btec= benzenetetracarboxylic acid) (I) was hydrothermally synthesized from an aqueous solution of Zn(NO3)2 6H2O, (deta) and (btec). Compound I crystallizes in the monoclinic system with the P21/c space group. The unit cell parameters are a= 9.6716(5)Å, b= 14.3776(8)Å, c= 13.5306(8)Å, β= 105.311(3)°, Z= 4, V= 1814.71(18) Å3 and Dx= 1.657 g/cm3. The refinement converged into R= 0.045, Rw= 0.048. The structure, determined by single crystal X-ray diffraction, consists of a network of ZnO4 centers, tetrahedrally coordinated by pyromellitate anions giving rise to a two-dimensional sheet structure. The connectivity resembles a 4-connected network in which each Zn atom is connected to four btec anions and each btec anion is linked to four Zn2+ ions.

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Published

2013-05-03

Issue

Vol. 2 No. 4 (2013)

Section

Inorganic Chemistry

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