Synthesis, Crystal Structure and IR Spectrum studies of 2-(4-Methyl-2-phenyl-4,5-dihydro-oxazol-4-ylmethyl)- isoindole-1,3-dione

Authors

  • Alami Anouar Sidi Mohammed Ben Abdellah University Faculty of Science Dhar El Marhaz Laboratory of organic chemistry http://orcid.org/0000-0002-3951-9382
  • Khadim Dioukhane Doctoral Training “Bioactive Molecules, Health an d Biotechnology”, Center of Doctoral Studies “Sciences and Technology”, Faculty of Sciences Dhar El Mahraz – Sidi Mohammed Ben Abdellah University, Fez 30000, Morocco
  • Younas Aouine Organic Chemistry Laboratory, Faculty of Sciences, Ibn Zohr University, P.B 8106, Cité Dakhla, Agadir 80060, Morocco
  • Mohamed El Omari Physico-Chemistry of Condensed Matter Team, Faculty of Sciences, Moulay Ismaïl University, P.B. 11201, Zitoune Meknes, Morocco
  • Lahcen El Ammari Laboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux, Faculty of Sciences, Mohammed V University in Rabat, Avenue Ibn Batouta, B.P. 1014, Rabat, Morocco
  • Mohamed Saadi Laboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux, Faculty of Sciences, Mohammed V University in Rabat, Avenue Ibn Batouta, B.P. 1014, Rabat, Morocco
  • Abderrazzak Assani m.saadi6@yahoo.fr
  • Rachid Ouarsal Laboratory of Engineering of Organometallic and Molecular Materials, Unit Associated with CNRST (URAC19), Faculty of Sciences Dhar El Mahraz – Sidi Mohammed Ben Abdellah University, Fez 30000, Morocco.

DOI:

https://doi.org/10.13171/mjc92190916245aa

Abstract

The organo-amino compound of title 2-(4-methyl-2-phenyl-4,5-dihydro-oxazol-4-ylmethyl)-isoindole-1,3-dione was synthesized by the mixture of (4-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)methyl-4-methylbenzenesulfonate and isoindoline-1,3-dione in N,N-dimethylformamide with a yield of around 65%. The structural study of the compound, C19H16N2O3, is realized using single crystal X-Ray diffraction which shows that this compound crystallizes in the monoclinic system (P21/c, Z = 4) with the unit cell parameters: a = 14.3728 (13) Ã…, b = 9.6829 (10) Ã…, c = 11.8964 (12) Ã… and β = 107.384 (3). The refinement of the structure by the least-squares method with complete matrix leads to the following reliability factors R/Rw are 0.044/0.130.In the crystal, the molecules are linked together by hydrogen bonds and π…π interactions.The Infrared spectroscopic studies show the bands confirming the presence of the groups C=O, C-O, C-N, -CH3, -CH2 and =CH. 

Author Biographies

Alami Anouar, Sidi Mohammed Ben Abdellah University Faculty of Science Dhar El Marhaz Laboratory of organic chemistry

Professor of Higher Education

Khadim Dioukhane, Doctoral Training “Bioactive Molecules, Health an d Biotechnology”, Center of Doctoral Studies “Sciences and Technology”, Faculty of Sciences Dhar El Mahraz – Sidi Mohammed Ben Abdellah University, Fez 30000, Morocco

Doctoral student

Younas Aouine, Organic Chemistry Laboratory, Faculty of Sciences, Ibn Zohr University, P.B 8106, Cité Dakhla, Agadir 80060, Morocco

Assistant professor

Mohamed El Omari, Physico-Chemistry of Condensed Matter Team, Faculty of Sciences, Moulay Ismaïl University, P.B. 11201, Zitoune Meknes, Morocco

Professor of Higher Education

Lahcen El Ammari, Laboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux, Faculty of Sciences, Mohammed V University in Rabat, Avenue Ibn Batouta, B.P. 1014, Rabat, Morocco

Professor of Higher Education

Mohamed Saadi, Laboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux, Faculty of Sciences, Mohammed V University in Rabat, Avenue Ibn Batouta, B.P. 1014, Rabat, Morocco

Professor of Higher Education

Abderrazzak Assani, m.saadi6@yahoo.fr

Professor of Higher Education

Rachid Ouarsal, Laboratory of Engineering of Organometallic and Molecular Materials, Unit Associated with CNRST (URAC19), Faculty of Sciences Dhar El Mahraz – Sidi Mohammed Ben Abdellah University, Fez 30000, Morocco.

Assistant professor

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Published

2019-09-16

Issue

Section

Organic Chemistry