Application of the solid-phase micro-extraction technique coupled to GC-MS in the control of the impact of the pest treatment products in the industrial unit on the industrialized food products Quality

Authors

  • Ahmed Lakhili Faculté des sciences RABAT
  • Abdelkbir Bellaouchou Faculté des sciences RABAT
  • Abdallah El Abidi INSTITUT NATIONAL D’HYGENE
  • Mohammed El Idrissi Chouaïb Doukkali University, El Jadida, Morocco
  • Mohammed Fekhaoui institut scientifique de rabat. morroco

DOI:

https://doi.org/10.13171/mjc851907031al

Abstract

In this investigation, solid phase extraction (SPME) is applied in order to determine the concentrations of insecticides and rat poisons detected in the samples taken on the industrial finished product. Gas chromatography, coupled with mass spectroscopy (GC-MS) is used as an analytical instrument for this purpose. In order to obtain an optimal extraction, different process parameters are examined and optimized. Relevant results are obtained using 30 minutes non-specific binding property time, with 30 minutes stirring mode with magnetic stirring and a temperature of 30 °C. The efficiency of insecticides, poisons for rats, has been demonstrated and pesticides are likely to be at a high concentration in finished industrial products.

References

- A. Lakhili, M. Fekhaoui, A. Bellaouchou, A. El Abidi, L. Tahri, SPME Extraction Methods of Doped Organochlorine Pesticides in Moroccan Water Samples, Mediterranean Journal of Chemistry 2018, 7(4), 294-302.

- R.I. Bonansea, M.V. Amé, D.A. Wunderlin, Solid-phase microextraction and gas chromatography with mass spectrometric detection for the determination of pesticides in aqueous samples, Journal of Chromatography A, 2013, 795, 105-115.

- C. L. Arthur, J. Pawliszyn, Solid Phase Microextraction with thermal desorption using fused silica optical fibers, Analytical Chemistry, 1990, 62, 2145-2148.

- R. A. Dong, P. L. Liao, Determination of organochlorine pesticides and their metabolites in soil samples using headspace solid-phase microextraction, Journal of Chromatography A, 2001, 918, 177-188.

- C. P. Dougherty, S. H. Holtz, J. C. Reinert, L. Panyacosit, D. A. Axelrad, T. J. Woodruff, Dietary exposures to food contaminants across the United States, Environmental Research, 2000, 84, 170-180.

- J. H. Jelen, M. Majcher, M. Dziadas, Multi-residue detection of pesticides in juice and fruit wine: A review of extraction and detection methods, Food Research International, 2012, 46, 399-409.

- R. P. Berladi, J. Pawliszyn, The application of chemically modified fused silica fibers in the extraction of organics from water matrix samples and their rapid transfer to capillary columns Environmental Science and Pollution Research, 1989, 24, 179-191.

- R. Botter, G. Bouchoux, Techniques de l'ingénieur, Spectrométrie de masse, Determination of chlorinated pesticides in water by SPME/GC, Water Research, 2002, 36, 1909-1911.

- H. Shahsavand, M. R. Nateghi, Analysis of chlorothalonil and degradation products in soil and water by GC/MS and LC/MS. Chemosphere, Journal of Water Chemistry and Technology, 2018, 04, 86-90.

- S. Chen, S. Lili, S. Zhengjun, H. Qiuhui, Determination of organochlorine pesticide residues in rice and human and fish fat by simplified two-dimensional gas chromatography, Food Chemistry, 2007, 104, 1315-1319.

- C. De Rossi, R. Bierl, J Riefstahl, Organic pollutants in precipitation: monitoring of pesticides and polycyclic aromatic hydrocarbons in the region of Trier (Germany), Physics and Chemistry of the Earth, 2003, 28, 307-314.

- A. Derouiche, M. R. Driss, J. P. Morizur, M.H. Taphanel, Simultaneous analysis of polychlorinated biphenyls and organochlorine pesticides in water by headspace solid-phase microextraction with gas chromatography-tandem mass spectrometry, Journal of Chromatography A, 2007, 1138, 231-300.

- M. Fernández, C. Padrón, L. Marcon, S. Ghini, R. Colombo, A. G. Sabatini, S. Girotti, Determination of organophosphorus pesticides in honeybees after solid-phase microextraction, Journal of Chromatography A, 2001, 922, 257-265.

- C. Ferrer, M. J. Gómez, J. F. Garc í­a-Reyes, I. Ferrer, E. M. Thurman, A.R. Fernández-Alba, Determination of pesticide residues in olives and olive oil by matrix solid-phase dispersion followed by gas chromatography/mass spectrometry and liquid chromatography/tandem mass spectrometry, Journal of Chromatography A, 2005, 1069, 183-194.

- J. Fillion, F. Sauvé, J. Selwyn, Multiresidue method for the determination of residues of 251 pesticides in fruits and vegetables by gas chromatography/mass spectrometry and liquid chromatography with fluorescence detection, Journal of AOAC INTERNATIONAL, 2000, 83, 698-750.

- H. Shahsavand, M. R. Nateghi, Solid Phase Extraction and Flame Atomic Absorption Determination of Cadmium in Water Samples, Journal of Water Chemistry and Technology, 2018, 86-90.

- S.A. Harris, M.J. Whiticar, M.K. Eek, Molecular and isotopic analysis of oils by solid phase microextraction of gasoline range hydrocarbons, Organic Geochemistry 1999, 30, 721-737.

- F. Herná¡ndez, O. J. Pozo, J. V. Sancho, L. Bijlsma, M. Barreda, E. Pitarch, Multiresidue liquid chromatography-tandem mass spectrometry determination of 52 non-gas chromatography-amenable pesticides and metabolites in different food commodities, Journal of Chromatography A, 2006, 1109, 242-252.

- M.C. Sampedro, O. Martin, C. Lopez de Armentia, M.A. Goicolea, E. Rodriguez, Z. Gomez de Balugera, J. Costa-Moreira, R. J. Barrio, Solid-phase microextraction for the determination of systemic and non-volatiles pesticides in river water using gas chromatography with nitrogen-phosphorus and electron-capture detection, Journal of Chromatography A, 2000, 893, 347-358.

- F. J. Santos, M. T. Galceran, The application of gas chromatography to environmental analysis Trends in Analytical Chemistry. 2002, 2, 672-685.

- A. Yang, J. Zhao, J. Wang, H. Yu, H. Piao, D. Li, Water-based gas purge microsyringe extraction coupled with liquid chromatography for determination of alkylphenols from seafood Laminaria japonica Aresh, Journal of Chromatography A, 2018,1300, 302-360.

- J.G. Eskenazi, E. A. Gladstone, A. Bradman, L. Pedersen, C. Johnson, D. B. Barr, Scientific Reports volume 8., Association between in utero organophosphate pesticide exposure and abnormal reflexes in neonates, NeuroToxicology, 2018, 26, 1167-1180.

Downloads

Published

2019-07-03

Issue

Section

Analytical Chemistry