Chemical preparation, thermal behavior and infrared studies of the new cyclotriphosphate tetrahydrate of manganese and distrontium, MnSr2(P3O9)2.4H2O

Authors

  • Smail EL Makhloufy Laboratoire de Chimie-Physique des Matériaux, Faculté des Sciences Ben M'Sik B. P. 7955, Hassan II University of Casablanca, Casablanca, Maroc
  • Malika Tridane Laboratory of Chemistry-Physics of Materials, Faculty of Sciences Ben M'Sik B. P. 7955, Hassan II University of Casablanca, Casablanca, Morocco. Laboratory of Chemistry-Physics of Materials, Faculty of Sciences Ben M'Sik B. P. 7955, Hassan II University of Casablanca, Casablanca, Morocco.
  • El Mehdi Majdi Laboratory of Chemistry-Physics of Materials, Faculty of Sciences Ben M'Sik B. P. 7955, Hassan II University of Casablanca, Casablanca, Morocco.
  • Hamza Marouani Laboratory of Chemistry-Physics of Materials, Faculty of Sciences Ben M'Sik B. P. 7955, Hassan II University of Casablanca, Casablanca, Morocco.
  • Soufiane Zerraf Laboratory of Chemistry-Physics of Materials, Faculty of Sciences Ben M'Sik B. P. 7955, Hassan II University of Casablanca, Casablanca, Morocco.
  • Mustafa Belhabra Laboratory of Chemistry-Physics of Materials, Faculty of Sciences Ben M'Sik B. P. 7955, Hassan II University of Casablanca, Casablanca, Morocco.
  • Abdelouahed Cherqaoui Laboratory of Chemistry-Physics of Materials, Faculty of Sciences Ben M'Sik B. P. 7955, Hassan II University of Casablanca, Casablanca, Morocco.
  • Said Belaaouad Laboratory of Chemistry-Physics of Materials, Faculty of Sciences Ben M'Sik B. P. 7955, Hassan II University of Casablanca, Casablanca, Morocco.

DOI:

https://doi.org/10.13171/mjc941911141082sem

Abstract

A new cyclotriphosphate tetrahydrate of manganese and distrontium, MnSr2(P3O9)2.4H2O, was obtained as a polycrystalline sample by the method of ion-exchange resin. The cyclotriphosphate studied in this work is the second one having the formula MnSr2(P3O9)2.4H2O after BaZn2(P3O9)2.10H2O. Its crystallographic characterization, infrared studies and thermal behavior are given. The studied phosphate crystallizes in the triclinic system, P-1, with the following unit cell parameters : a = 6,653(1)Å, b = 7,110(1)Å, c = 5,123(1)Å, a = 103,37(2)°, b = 95,81(2)°,  g = 93,04(2)° and Z = 1. The intermediate products of dehydration of MnSr2(P3O9)2.4H2O are MnSr2(P3O9)2.2H2O, mixture of ([Mn(PO3)2]∞ + 2g [Sr(PO3)2]∞) and mixture of ([Mn(PO3)2]∞ + 2b[Sr(PO3)2]∞). The thermal behavior of the studied condensed phosphate has been investigated and interpreted by IR absorption and X-ray diffraction experiments. The title compound can be used as catalyst, ion exchanger, the reactant in ionic conditions, intercalation reactions, superphosphate fertilizer and as an inorganic pigment in ceramics.

Author Biography

Smail EL Makhloufy, Laboratoire de Chimie-Physique des Matériaux, Faculté des Sciences Ben M'Sik B. P. 7955, Hassan II University of Casablanca, Casablanca, Maroc

Département de chimie

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Published

2019-11-14

Issue

Vol. 9 No. 4 (2019)

Section

Materials Chemistry

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