Thermal characterization and comparisons of lignin-formaldehyde and lignin-glyoxal adhesives

Authors

  • Mohamed Ammar Materials, Environment and Energy Laboratory, Faculty of Sciences of Gafsa, University Gafsa -Tunisia
  • Ramzi Khiari Research Unity of Applied Chemistry & Environment, Department of Chemistry, Faculty of Sciences, University of Monastir, 5019 Tunisia.
  • Mohamed Naceur Belgacem 3Laboratoire de Génie des Procédés Papetiers (LGP2), UMR CNRS 5518, Grenoble INP-Pagora – 461, rue de la papeterie – 38402 Saint-Martin-d’Hères, France
  • Elimame Elaloui Materials, Environment and Energy Laboratory, Faculty of Sciences of Gafsa, University Gafsa -Tunisia

DOI:

https://doi.org/10.13171/mjc.2.6.2014.20.03.11

Abstract

In the present study, the main focus was the use of lignin isolated through an industrial waste (black liquor) to prepare phenolic-type resins. Thermal properties of control lignin-formaldehyde adhesive (RLF) and lignin –glyoxal adhesive (RLG) have been investigated in detail. The effect of methylolation of lignin by formaldehyde and glyoxal have been studied using thermogravimetric analysis (TG) and differential scanning calorimetry (DSC). Methylolation has significant effect on the structure and the thermal stability of lignin. Rate of curing is enhanced by the type of curing agent and temperature.

References

- L. Hong, A. Pizzi, Journal of Applied Polymers Science, 2008, 107, 203–209.

- A. Hüttermann, C. Mai, A. Kharazipour, Applied Microbiology and Biotechnology. 2001, 55, 387–394.

- L. I. Crishechko, G. Amaral-Labat, A. Szczurek, V. Fierro, B. N. Kuznetsov, A.Celzard, Microporous and Mesoporous Materials. 2013, 168, 19-29.

- Y. Tingting, X. Yingqi, Y.Chongwen, Journal of Applied Polymers Science. 2009,114, 1896–1901.

- Z. Xuebing, D. Lingmei, L. Dehua, Journal of Applied Polymers Science. 2009,114, 1295–1302.

- G. A. Amaral-Labat, A. Pizzi, A. Gonc, R. Alves, A. Celzard, S. Rigolet, G. J. M. Rocha, Journal of Applied Polymers Science. 2008, 108, 624–632.

- N.-E. El Mansouri, A. Pizzi, J. Salvado, Journal of Applied Polymers Science, 2007, 103, 1690–1699.

- A. K. Mozaffar, M. Sayed, M. Ashraf, P. Ved, Journal of Applied Polymers Science. 2004, 92, 3514–3523.

- S. Pingan, C. Zhenhu, M. Qingrong, F. Shenyuan, F. Zhengping, W. Qiang, Y. Jiewang, Journal of Macromolecular Science, Part B: Physics. 2012, 51, 720–735.

- G. Anna, G. Goran, Nordic Pulp and Paper Research Journal. 1999, 14, 163-170

- M. A. Khan, S. M. Ashraf, Journal of Thermal Analysis and Calorimetry.2007,89, 3, 993–1000.

- Y. N. Sazanov, E. N. Popova, G. N. Fedorova, V. E. Yudin, Russian Journal of Applied Chemistry.2011, 84, 1233-1237.

- H.R. Mansouri, P. Navarrete, A. Pizzi, S. Tapin-Lingua, B. Benjelloun-Mlayah, H. Pasch, S. Rigolet, European Journal of Wood and Wood Products. 2011,69, 221-229.

-H. William, B. O. Francielli, G. Stephane, S. Bernard, F. Elisabete, C. Alain, Macromolecular Materials and Engineering. 2006, 291, 829–839.

- C. Esposito Corcione, P. Prinari, D. Cannoletta, G. Mensitieri, A. Maffezzoli, International Journal of adhesives and adhesion. 2008, 28,91-100.

- C. Esposito Corcione, G. Mensitieri, Polymer Engineering and Science. 2009, 49,1708-1718.

- C. Esposito Corcione, A. Maffezzoli, ThermochimicaActa.2009, 485, 43-48.

Downloads

Published

2014-03-20

Issue

Vol. 2 No. 6 (2014)

Section

Physical Chemistry

License

Authors who publish with this journal agree to the following terms:

    1. Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal
    2. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal
    3. Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).