Fluorescence study, Raman spectroscopy, crystal structure, antimicrobial and antioxidant activities of cobalt (III) complex with a tridentate coumarin ligand

Authors

  • Imen Ketata Unité de Recherche de Chimie des Matériaux et de l’Environnement, UR11ES25, ISSBAT Université de Tunis El Manar, 9, Avenue Dr. Zoheir SAFI, 1006 Tunis, Tunisia
  • Taroub Bouzaiene INSAT, Université de Carthage Centre Urbain Nord, BP 676, Tunis-Cedex 1080 Tunis, Tunisia
  • Taicir Ben Ayed Unité de Recherche de Chimie des Matériaux et de l’Environnement, UR11ES25, ISSBAT Université de Tunis El Manar, 9, Avenue Dr. Zoheir SAFI, 1006 Tunis, Tunisia
  • Rached Ben Hassen Unité de Recherche de Chimie des Matériaux et de l’Environnement, UR11ES25, ISSBAT Université de Tunis El Manar, 9, Avenue Dr. Zoheir SAFI, 1006 Tunis, Tunisia

DOI:

https://doi.org/10.13171/mjc.3.1.2014.08.04.14

Abstract

Cobalt (III) complex diamine chloride was obtained from the reaction of Co (OAc)2, 4H2O; ethylene diamine and 3-acetyl-4-hydroxy-chromene- 2-one. The obtained product was characterized by Raman scattering, fluorescence and UV-visible spectroscopy. The room temperature structure was determined by single-crystal X-ray diffraction. The purity of the product was checked by X-ray powder diffraction analysis. Rietveld refinement using powder XRD confirms structure model determined by single-crystal X-ray diffraction (space group Pcca, a = 20.599(2) Å, b = 7.888(4) Å, c = 18.3820(1) Å and Z = 4). The metal complex was checked for its antimicrobial activity using well diffusion method and shows significant results by comparison with commercial antibiotics. Antioxidant tests indicate that the complex is an effective DPPH radical scavenger with an IC50 value of 26.32 μM.

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Published

2014-04-12

Issue

Vol. 3 No. 1 (2014)

Section

Organometallic Chemistry

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