Removal of heavy metals from synthetic solution by electrocoagulation

Authors

  • Mohamed Ilou laboratoire d’Électrochimie appliquée département chimie Faculté des sciences université chouaib doukkali El Jadida Maroc
  • Fatima Abida laboratoire d’Électrochimie appliquée département chimie Faculté des sciences université chouaib doukkali El Jadida Maroc
  • Zineb Hatim laboratoire d’Électrochimie appliquée département chimie Faculté des sciences université chouaib doukkali El Jadida Maroc
  • Abdelmoula Kheribech laboratoire d’Électrochimie appliquée département chimie Faculté des sciences université chouaib doukkali El Jadida Maroc

Abstract

The objective of this work concerns the optimization of the operating conditions for the removal of heavy metals from synthetic solution by Electrocoagulation (EC). To reach this purpose, we prepared a synthetic wastewater containing certain heavy metals (Ni, Cu, Zn, Fe and Pb) to study the influence of various parameters (conductivity, pH, time of electrolysis, current density and the initial concentration of the metal) on the rate of removal of these metals. The results show that this rate of removal can reach 99.9 % in the following optimal conditions: pH included between 6 and 8 and a density of the current of 1~1.5A / dm2. This study shows that it is possible to remove metals in aqueous solution by the technique of electrocoagulation. 

References

- R.C. Chenh, J.Am.Water Works Assoc., 1994, 86.79.

- L.Hartinger ,Handbuch der Abwasser- und Rcyclingtechnik,CarlHanserVerlag, Munchen-Wien,(1991).

- D.J. Chang and S.T. Hwang, Sep. Sci.Technol., 1996, 31,1831.

- D. Green and J. Menller , Method for removing sulfates and metal ions from waters and waste waters, PCT Int . Appl.WO 00 00273(2000).

- E. Wilkins, Q. Yang, J. Env. Sci. Health, 1996, A31, 2111.

- G. Bereket, A. Aroguz, M. Özel, J. Colloid. Appl. Sci., 1997, 187,338.

- A. Brady , Environ .Technol., 1994, 15, 429.

- B. W. Atkison, F. Bux, L. Kasen, Water Sci. Technol., (G.B), 1996, 34, 9.

- W. Phutdhawong, S. Chowwanapoonpohn, D. Buddhasukh, Electrocoagulation and subsequent Recovery of Phenolic compounds, Anal. sci., 2000, Vol. 16 , 1083.

- D. Harvey, Modern Analytical Chemistry Boston Burr Ridge : McGraw-Hill Companies,Inc.,(2000).

- M.Y.A. Mollah, R. Schennach, J.R. Parga, D.L. Cocke, Electrocoagulation science and applications, J. Hazard. Mat., 2001, Vol. 84, 29-41.

- N.V. Sidgwick, The chemical elements and their compounds, London, Oxford University Press(1962)

- X. Chen, G.Chen, P.L Yue, Separation of pollutants from restaurant wastewater by electroagualtion, Sep Technol., 2000, 19, 65-76.

- T. Picard, G. Gathalifaud-Feuillade, M. Mazet, C. Vandensteendam, Cathodic dissolution in the electrocoagulation process using aluminium electrodes, J. Environ. Monit., 2000, 2, 77-80.

- P. Canizares, F. Martinez, C. Jimenez, J. Lobato, M.A. Rodrigo, Comparison of the Al speciation in chemical and electrochemical processes, Ind. Eng. Chem. Res., 2006, 45, 8749-8750.

- B. Merzouka,, B. Gourich, A. Sekki, and col. Removal turbidity and separation of heavy metals using electrocoagulation-electroflotation technique A case study. J. Hazard. Mat., 2009, vol. 164, 215-222.

- C. H. Huang, L. Chen, C. L. Yang, Effect of anions on electrochemical coagulation for cadmium removal, Sep. Purif. Technol., 2009, 65, 137-146.

- Ö. Hanay, H. Hasar, Effect of anions on removing Cu2+, Mn2+ and Zn2+ in electro-coagulation process using aluminum electrodes, J. Hazard Mat., 2011, 189 572-576.

- E. Bazrafshan, Performance evaluation of electrocoagulation process for removal of chromium (VI) from synthetic chromium solutions using iron and Al electrodes, Turk. J. Eng. Environ. Sci., 2008, 32, 59-66.

- M.S. Bhatti, A.S. Reddy, A.K. Thukral, Electrocoagulation removal of Cr (VI) from simulated wastewater using response surface methodology, J. Hazard. Mater., 2009, 172, 839-846

- O.T. Can, M. Bayramoglu, The effect of process conditions on the treatment of benzoquinone solution by electrocoagulation,J. Hazard. Mater., 173 (2010), pp. 731-736.

- F. Akbal, S. Camc, Comparison of electrocoagulation and chemical coagulation for heavy metal removal, Chem. Eng. Technol., 2010, 33(10), 1655-1664.

- M. Behbahani, M.R. Alavi Moghaddam, M. Arami, Fluoride removal by electro-coagulation process: optimization through response surface methodology Desalination, 2011, 271, 209-218.

- A.H. El-Shazly, A.A. Al-Zahrani, S.S. Al-Shahrani, Improvement of NO3- removal from wastewater by using electrocoagulation unit with vertical monopolar Al electrodes, Int. J. Electrochem. Sci., 2011, 6, 4141-4149.

- K. Dermentzis, A. Christoforidis, E. Valsamidou, Removal of Ni,Cu,Zn and Cr from synthetic and industrial wastewater by electro coagulation, J. Environ. Sci., 2011,1, 697- 710.

- S. Bellebia, S. Kacha, A. Z. Bouyakoub, Z. Derriche, Experimental investigation of chemical oxygen demand and turbidity removal from cardboard paper mill effluents using electro coagulation and adsorption processes, Environ. Prog. Sustain. Energy, 2012, 31(3), 361-370.

- E-S. Z. El-Ashtoukhy, Y.A. El-Taweel, O. Abdelwahab2 , E.M.Nassef, Treatment of petrochemical waste water containing phenolic compounds by electro coagulation, Int. J. Electrochem. Sci., 2013, 8, 1534-1550.

- A. R. Amani-Ghadima, S. Abera, and col. Optimization of electrocoagulation process for removal of an azo dye using response surface methodology , Chem. Eng. Process., 2013, 64, 68-78.

- A.K. Chopra, A.K. Sharma, Removal of turbidity, COD and BOD from secondarily treated sewage water by electrolytic treatment, Appl. Water Sci., 2013, 3, 125-132.

- Y.T. Chung, L.N. Ng, A.W. Mohammad, Sulfonated-polysulfone membrane surface modifica- tion by employing methacrylic acid through UV-grafting, J. Ind. Eng. Chem., 2014, 20,1549-1557.

- I. Elksibi, W. Haddar, M.B. Ticha, R. Gharbi, M. Mhenni, Development and optimisation of a non conventional extraction process of natural dye from olive solid waste using response surface methodology, Food Chem., 2014, 161, 345-352.

- A. Fakhri, Investigation of Hg(II) adsorption from aqueous solution onto copper oxide nano particles: optimization using response surface methodology, Process Saf. Environ., 2015, 93, 1-8. DOI: 10.1016/j.psep.2014.06.003.

- S. Vasudevan, M.A. Oturan, Electrochemistry as Cause and Cure in Water Pollution. An Overwiew. Environmental Chemistry Letters, Springer Verlag, 2013, DOI: 10.1007/s10311-013-0434-2.

- G. Sozhan, S. Mohan , S. Vasudevan, R. Balaji, S. Pushpavanam. Recovery of Chromium from the Solid Residue by In-Situ-Generated Hypochlorite. Ind. Eng. Chem. Res., 2006, 45 (23), pp 7743-7747.

- R. Kamaraj, S.Vasudevan. Evaluation of electrocoagulation process for the removal of strontium and cesium from aqueous solution Chemical Engineering Research and Design, 2015, 93, 522-530.

- S. Vasudevan, J. Lakshmi, G. Sozhan. Studies on the Al–Zn–In-alloy as anode material for the removal of chromium from drinking water in electrocoagulation process. Desalination, 2011, 275, 260-268.

- J. Lakshmi, S. Vasudevan. Graphene a promising material for removal of perchlorate (ClO4 −) from water. Environmental Science and Pollution Research, 2013, 20, 5114-5124.

- S. Vasudevan, G. Sozhan, S. Mohan, R. Balaji, P. Malathy. Electrochemical Regeneration of Chromium Containing Solution from Metal Finishing Industry. Ind. Eng. Chem. Res., 2007, 46, 2898-290.

- S.Vasudevan, J. Lakshmi, R. Vanathi, Electrochemical Coagulation for Chromium Removal: Process Optimization, Kinetics, Isotherms and Sludge Characterization Clean-Soil, Air, 2010, 38, 9-16.

- S. Vasudevan, J. Lakshmi, Studies relating to an electrochemically assisted coagulation for the removal of chromium from water using zinc anode. Water Science and Technology: Water supply, 2011, 11 (2), 142-150; DOI: 10.2166/ws.2011.032.

- P. Ganesan, R. Kamaraj, S.Vasudevan. Application of isotherm, kinetic and thermodynamic models for the adsorption of nitrate ions on graphene from aqueous solution. Journal of the Taiwan Institute of Chemical Engineers, 2013, 44, 808-814.

Downloads

Published

2016-05-31

Issue

Section

Environmental Chemistry