New polyacylhydrazone dynamers incorporating furan moieties

Authors

  • Ichraf Jarraya Laboratory of Applied Chemistry HCGP, Faculty of Science, University of Sfax, 3000 Sfax Tunisia
  • Imen Abdelhedi Laboratory of Applied Chemistry HCGP, Faculty of Science, University of Sfax, 3000 Sfax Tunisia
  • Majdi Abid Laboratory of Applied Chemistry HCGP, Faculty of Science, University of Sfax, 3000 Sfax Tunisia
  • Souhir Abid Laboratory of Applied Chemistry HCGP, Faculty of Science, University of Sfax, 3000 Sfax Tunisia

DOI:

https://doi.org/10.13171/mjc.2.6.2014.08.03.23

Abstract

Solution polycondensation of furanic dihydrazides with different bridging groups, in conjunction with terephthaldehyde or isophthaldehyde, gave high yields of a novel series of furanic polyacylhydrazones with high molecular weights. The polymers were characterized by solubility tests, viscosity measurements, 1H and 13C NMR, FTIR spectroscopies and thermogravimetric analysis. The polyacylhydrazones obtained had inherent viscosities in the range of 0.52-1.21 dL/g, and were easily dissolved in common polar solvents. The glass-transition temperatures of these polymers were recorded between 201 and 232°C. Decomposition temperature for 10% weight loss all occurred above 352°C in nitrogen atmosphere.

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Published

2014-08-03

Issue

Vol. 2 No. 6 (2014)

Section

Polymer Chemistry

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