Synthesis, characterization and crystal structure of new cobalt (III) complex: [Tris(1,10-phenanthroline-κ2N,N’) Cobalt (III)] trinitrate monohydrate [Co(C12H8N2)3](NO3)3.H2O

Authors

  • Jawher Abdelhak Laboratoire de Matériaux et Cristallochimie, Département de Chimie, Faculté des Sciences de Tunis, Université de Tunis El Manar 2092 Tunis, Tunisie
  • Saoussen Namouchi Cherni Laboratoire de Matériaux et Cristallochimie, Département de Chimie, Faculté des Sciences de Tunis, Université de Tunis El Manar 2092 Tunis, Tunisie
  • Mohamed Faouzi Zid Laboratoire de Matériaux et Cristallochimie, Département de Chimie, Faculté des Sciences de Tunis, Université de Tunis El Manar 2092 Tunis, Tunisie

DOI:

https://doi.org/10.13171/mjc.3.1.2014.26.03.22

Abstract

We report herein the synthesis and the physicochemical characterization of a new cobalt(III) complex of formula [Co(C12H8N2)3](NO3)3.H2O. This compound has been prepared by slow evaporation at room temperature and characterized by single crystal X-ray diffraction, IR, UV-VIS spectra and thermal analysis (TG and DTA). Structural cohesion is established essentially by π-π interactions between the rings of phenanthroline groups and intermolecular hydrogen bonds connecting the nitrate entities and uncoordinated water molecules.

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Published

2014-03-26

Issue

Vol. 3 No. 1 (2014)

Section

Coordination Chemistry

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