Preparation and Characterization of NaA Zeolite Membranes and its Application for Removal of Heavy Metals

Authors

  • Najib Tijani Equipe : Membranes, Matériaux et Procédés de Séparation, Département de Chimie, Faculté des Sciences, Université Moulay Ismaîl, Meknès, Morocco
  • Hammou Ahlafi Equipe : Matériaux et Catalyse Appliqués, Département de chimie, Laboratoire de Chimie et Biologie Appliquées à l’Environnement, Faculté des Sciences, Université Moulay Ismaîl, Meknès, Morocco
  • Monique Smaihi Institut Européen des Membranes, CNRS, UMR 5635 CC 047, Place Eugène Bataillon, 34 095 Montpellier cedex5, France
  • Abdeslam El Mansouri Institut Européen des Membranes, CNRS, UMR 5635 CC 047, Place Eugène Bataillon, 34 095 Montpellier cedex5, France

DOI:

https://doi.org/10.13171/mjc.2.3.2013.06.01.00

Abstract

In this work, the characteristics of low cost NaA zeolite membranes for heavy metal removal from synthesised solutions are presented. These membranes were elaborated on a clay macroporous support which were prepared and characterized by XRD, SEM and N2 permeation. The effects of synthesis parameters such as temperature T and time t on the proprieties of the NaA zeolite membranes were investigated. The best experimental conditions for synthezised membranes are obtained for T = 60 °C, t = 24 h and 117 L m-2 h-1 bar-1 for a water flux of membrane.The tests for the removal of Pb(II), Zn(II) and Cr(VI), conducted on these NaA zeolite membranes, show respectively the rejection reached 99%, 99% and 12% after 1 hour of filtration at 7 bars of N2 and at ambient temperature.

References

Y. Li, H. Chen, J. Liu, W. Yang, Journal of Membrane Science, 2006, 277, 230 – 239

S. Dominguez, A. Berenguer-Murcia, E. Morallon, A. Linares-Solano, D. Cazorla-Amoros, Microporous and Mesoporous Materials, 2008, 115, 51- 60

J. Caro, M. Noack, Microporous and Mesoporous Materials, 2008, 115, 215–233

X. Chen, W. Yang , Journal of Membrane Science, 2008, 316, 3-17

E.E. McLeary, J.C. Jansen, F. Kapteijn, Microporous and Mesoporous Materials, 2006, 90, 198–220

A. Huang, N. Wang, J. Caro, Microporous and Mesoporous Materials, 2012, 164, 294-301

I. Tiscornia, I. Kmakiri. Bredesen, C. Téllez, J. Coronas, Separation and Purification Technology, 2010, 73, 8-12

P. Chen, X. Chen, X. Chen, H. Kita, Journal of Membrane Science, 2009, 330, 369–378

X. Chen, W. Yang , J. Liu, L. Lin, Journal of Membrane Science, 2005, 255, 201- 211

L.T.Y. Au, K.L. Yeung, Journal of Membrane Science, 2001, 194, 33 – 55

K. Sato, K. Sugimoto, N. Shimotsuma, T. Kikuchi, T. Kyotani, T. Kurata, Journal of Membrane Science, 2012, 409 – 410, 82 – 95

L. Li, J. Dong, T. M. Nenoff, R. Lee, Desalination by reverse osmosis using MFI zeolite membranes, Journal of Membrane Science, 2004, 243, 401- 404

A. Malekpour, M.R. Millanib, M. Kheirkhah, Desalination, 2008, 225, 199 - 208

L. Zhang, Y-Hong. Zhao, R. Bai, Journal of Membrane Science, 2011, 379, 69–79

E. Katsou, S. Malamis, M. Loizidou, Bioresource Technology, 2011, 102, 4325 – 4332

C. Mbareck, Q.T. Nguyen, O. T. Alaoui, D. Barillier, Journal of Hazardous Materials, 2009, 171, 93–101

Y. Anbri, N. Tijani, J. Coronas, E. Mateo, M. Menéndez, J. Bentama, Desalination, 2008, 221, 419 - 424

N. Saffaj, M. Persin, S.A.Younsi, A. Albizane, M. Cretin, A. Larbot, Applied Clay Science, 2006, 31, 110 –119

M. Khayet, C. Y. Feng, K. C. Khulbe, T. Matsuura, polymer, 2002, 40, 3879 - 3890

X. Xu, W. Yang, J. Liu, L. Lin, N. Stroh, H. Brunner, Journal of Membrane Science, 2004, 229, 81- 85

E.I. Basaldella, P.G. Vázquez, F. Iucolano, D. Caputo, Journal of Colloid and Interface Science, 2007, 313, 574 – 578

D. Vasanth, G. Pugazhenthi, R. Uppaluri, Desalination, 2012, 285, 239–244

S. Sachdeva, A. Kumar, Journal of Membrane Science, 2008, 307, 37–52

Downloads

Published

2013-01-06

Issue

Section

Environmental Chemistry