Ternary cobalt complexes with amino acids: potentiometric study, modelization and solid-state investigation

Authors

  • Schahrazede Aomraoui Laboratoire d’Hydrométallurgie et Chimie Inorganique Moléculaire, U.S.T.H.B, B.P 32, El Alia, Algiers, Algeria
  • Achour Terbouche Laboratoire d’Hydrométallurgie et Chimie Inorganique Moléculaire, U.S.T.H.B, B.P 32, El Alia, Algiers, Algeria
  • Karim Beddar Laboratoire d’Hydrométallurgie et Chimie Inorganique Moléculaire, U.S.T.H.B, B.P 32, El Alia, Algiers, Algeria
  • Safia Djebbar Laboratoire d’Hydrométallurgie et Chimie Inorganique Moléculaire, U.S.T.H.B, B.P 32, El Alia, Algiers, Algeria
  • Ouassini Benali-Baitich Laboratoire d’Hydrométallurgie et Chimie Inorganique Moléculaire, U.S.T.H.B, B.P 32, El Alia, Algiers, Algeria
  • Gilles Bouet Laboratoire de Chimie de Coordination, Faculté de Pharmacie, 16 Boulevard Daviers, F-49100 Angers, France

DOI:

https://doi.org/10.13171/mjc.1.3.2011.02.10.23

Abstract

A study in solution of new ternary complexes of cobalt (II) with the tetradentate ligand Schiff base (N,N’-bis (2-hydroxy acetophenone) ethylenediimine; H2L) as primary ligand and the amino acid (histidine or tryptophan) as the secondary one has been realized by potentiometry. The stability constants of the complexes have been determined with the calculation program SIRKO. It has been found that the ternary complexes are more stable than the corresponding binary ones. The study has been completed by modelization of all the species found in solution by molecular mechanics with the program EMO (Energy of Molecule).The complexes isolated in powdered form were characterized by elemental analysis, molar conductance, IR spectra, magnetic and electronic spectra. The spectral results support the binding of H2L with two N and two O donor sites to cobalt ion and the binding of histidine or tryptophan by monodentate maner with O donor site, giving an octahedral geometry.Magnetic and Electronic results show that the Cobalt (II) has been oxidized to Co(III) and has a low spin configuration.

References

- S. Djebbar-Sid, O. Benali-Baitich, J. P. Deloume, J. Mol. Struct., 2001, 569, 121-128.

- L. Mishra, R. P. Krishna, K. Pandey, Spectrochim. Acta Part A: Mol. Biomol. Spectr.,2008, 70, 79-85.

- F. A. Cotton, G. Wilkinson, C. A. Murillo, M. Bochman, Advanced Inorganic Chemistry, 6th Ed. Wiley: New York, 1992, pp 829.

- A. Adkhis, S. Djebbar, O. Benali-Baitich, A. Kadri, M. A. Khan, G. Bouet, Synth. React.Inorg. Met.-Oeg.Chem., 2003, 33, 35-50.

- D. C. Ware, W. A. Denny, G. R. Clark, Acta. Cryst., 1997, 53, 1058-1059.

- H. Hamrit, S. Djebbar-Sid, O. Benali-Baitich, M. A. Khan, G. Bouet, Synth. React. Inorg. Met-Org. Chem., 2000, 30, 1835-1848.

- A. Rahman, L. Novel, Trans. Met. Chem, 2006, 31, 943-950.

- F. B. Ansari, M. Farooqui, S. H. Quadri, Rzayan J. Chem., 2010, 3, 359-362. 9- S. Belaid, S. Djebbar, O. Benali-Baitich, M. Khan, G. Bouet, C. R. Chim., 2007, 10,568- 572.

- G. Ibrahim, G. Bouet, I. H. Hall, M. A. Khan, J. Inorg. Biochem., 2000, 81, 29-34.

- B. Blaive, G. Legsai, R. Lai, J. Mol. Struct, 1995, 354, 245-250.

- E. Farkas, E. A. Enyedy, G. Micera, E. Garribba, Polyhedron, 2000, 19, 1727-1736.

- E. Farkas, H. Csoka, G. Micera, A. Dessi, J. Inorg. Biochem., 1997, 65, 281-286.

- A. Adkhis, O. Benali-Baitich, M. A. Khan, G. Bouet, Synh. React. Inorg. Met.-Org.Chem., 2000, 30, 1849-1858.

- R. J. Sundberg, R. B. Martin, Chem. Rev., 1974, 74, 471-490.

- X. J. Victor, J. D. Ranford, Inorg. Chim. Acta, 2000, 304, 38-44.

- W. J. Geary, Coord. Chem. Rev., 1971, 7, 81-122.

- L. J. Bellamy, The Infrared Spectra of Complex Molecules, 3rd Ed., J. Wiley: New York,1975, pp 226.

- N.V. Thakkar, J. R. Thakkar, Synh. React. Inorg. Met.-Org. Chem., 2000, 30, 1871-1887.

- R. Pradhan, S. Mukhopadhyay, D. C. Bera, C. Simonnet, F. Sécheresse, R. Bhattacharyya,Inorg. Chem. Com., 1999, 2, 495-497.

- R. L. De, K. Samanta, K. Maiti, E. Keller, Inorg. Chim. Acta, 2001, 316, 113-116.

- A. B. P. Lever, Inorganic Electronic Spectroscopy, 2nd Ed., Elsevier: Amstedam, 1984,pp 480, 508, 566.

- A. Terbouche, S. Djebbar, O. Benali-baitich, M. Khan and G. Bouet, Revue Roumaine de Chimie, 2008, 53, 101-106.

- N. Tidjani-Rahmouni, S. Djebbar-Sid, H. Hamrit, O. Benali-Baitich, J. Soc. Alger. Chim., 2001, 11, 121-130.

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Published

2011-10-02

Issue

Vol. 1 No. 3 (2011)

Section

Coordination Chemistry

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