The dielectric and electrical proprieties of Ethylcarbazole family based copolymer
DOI:
https://doi.org/10.13171/mjc8319050806mbAbstract
The dielectric and electrical proprieties of Ethylcarbazole family based copolymer such as Poly(Ethylcarbazole-Terphenyl) (PEcbz-Ter), Poly(Ethylcarbazole-Anthracene) (PEcbz-Ant) and Poly(Ethylcarbazole-Furan) (PEcbz-Fur) were investigated over the frequency range from 1 kHz to 2 MHz. The dielectric constant ε'r for (PEcbz-Ter), (PEcbz-Ant) and (PEcbz-Fur) pellets was found to decrease as the frequency increases and it was recorded a value of 11 7 , 11 6 and 7 6 respectively at 1 kHz. The dielectric loss was investigated and have a value below 1% at 11 kHz, which is suitable for several energy storage applications.References
- S. Bi, C. Lu, W. Zhang, F. Qiu, F. Zhang, Two-dimensional polymer-based nanosheets for electrochemical energy storage and conversion, J. Energy Chem., 2018, 27, 99-116.
- M. Wagner, T. Rębis, O. Inganäs, Enhancing charge storage of conjugated polymer electrodes with phenolic acids, J. Power Sources., 2016, 302, 324-330.
- F. Yang, C. Li, J. Zhang, G. Feng, Z. Wei, W. Li, Methylated conjugated polymers based on diketopyrrolopyrrole and dithienothiophene for high-performance field-effect transistors, Org. Electron. Phys. Mater. Appl., 2016, 37, 366-370.
- G. Zhang, R. Peng, P. Li, X. Wang, H. Lu, J. Yu, L. Qiu, Organic thin-film transistors based on thieno[3,4-c]pyrrole-4,6-dione conjugated polymer via oxidative polymerization, Synth. Met., 2013, 180, 73-78.
- O. Ninis, R. Kacimi, H. Bouaamlat, M. Abarkan, M. Bouachrine, Theoretical studies of photovoltaic properties for design of new Azo-Pyrrole photo-sensitizer materials as dyes in solar cells, J. Mater. Environ. Sci., 2017, 8, 2572-2578.
- H. Bouaamlat, O. Ninis, M. Abarkan, M. Bouachrine, DFT and TD-DFT studies of alkyl-substituted oligopyrroles for optoelectronic devices, J. Mater. Environ. Sci., 2017, 8, 2651-2656.
- A.T. Seyhan, Y. Göncü, O. Durukan, A. Akay, N. Ay, Silanization of boron nitride nanosheets (BNNSs) through microfluidization and their use for producing thermally conductive and electrically insulating polymer nanocomposites, J. Solid State Chem., 2017, 249, 98-107.
- L. Valentini, I. Armentano, J. Biagiotti, A. Marigo, S. Santucci, J.M. Kenny, AC conductivity of conjugated polymer onto self-assembled aligned carbon nanotubes, Diam. Relat. Mater., 2004, 13, 250-255.
- G. Garbay, L. Muccioli, E. Pavlopoulou, A. Hanifa, G. Hadziioannou, C. Brochon, E. Cloutet, Carbazole-based π-conjugated polyazomethines: Effects of catenation and comonomer insertion on optoelectronic features, Polymer., 2017, 119, 274-284.
- R.A. Irgashev, N.A. Kazin, N.I. Makarova, I. V. Dorogan, V. V. Malov, A.R. Tameev, G.L. Rusinov, A. V. Metelitsa, V.I. Minkin, V.N. Charushin, Synthesis and properties of new π-conjugated imidazole/carbazole structures, Dyes Pigments., 2017, 141, 512–520.
- A. Iraqi, I. Wataru, Preparation and Properties of 2, 7-Linked N -Alkyl-9 H -carbazole Main-Chain Polymers, 2004, 442-448.
- J. Oriou, F. Ng, G. Hadziioannou, C. Brochon, E. Cloutet, Synthesis and structure-property relationship of carbazole-alt-benzothiadiazole copolymers, J. Polym. Sci. Part Polym. Chem., 2015, 53, 2059-2068.
- M. Arbatti, X. Shan, Z. Cheng, Ceramic-polymer composites with high dielectric constant, Adv. Mater., 2007, 19, 1369-1372.
- W. Wan, J. Luo, C. e. Huang, J. Yang, Y. Feng, W.X. Yuan, Y. Ouyang, D. Chen, T. Qiu, Calcium copper titanate/polyurethane composite films with high dielectric constant, low dielectric loss and super flexibility, Ceram. Int., 2018, 44, 5086-5092.
- P. Brochu, Q. Pei, Advances in dielectric elastomers for actuators and artificial muscles, Macromol. Rapid Commun., 2010, 31, 10-36.
- Y. Shi, L. Huang, A.K. Soh, G.J. Weng, S. Liu, S.A.T. Redfern, A scaling law for distinct electrocaloric cooling performance in low-dimensional organic, relaxor and anti-ferroelectrics, Sci. Rep., 2017, 7, 1-9.
- H. Sadki, M.N. Bennani, K. Alimi, M. Bouachrine, Synthesis and Characterization of New Electroluminescent Material Based on Carbazole , and Terphenyle, 2014, 3, 11600-11611.
- Moha, Council for Innovative Research, J. Adv. Chem., 2014, 10, 2146-2161.
- C.J. Mathai, S. Saravanan, M.R. Anantharaman, S. Venkitachalam, S. Jayalekshmi, Characterization of low dielectric constant polyaniline thin film synthesized by ac plasma polymerization technique, 2002, 35, 240-245.
- O.E. Sherif, DFT calculations, electrical and thermal properties of unsubstituted triphenylformazan, Int. J. Electrochem. Sci., 2015, 10, 9751-9765.
- G.M. Treich, S. Nasreen, A. Mannodi Kanakkithodi, R. Ma, M. Tefferi, J. Flynn, Y. Cao, R. Ramprasad, G.A. Sotzing, Optimization of Organotin Polymers for Dielectric Applications, ACS Appl. Mater. Interfaces., 2016, 8, 21270-21277.
- G.E. Pike, ac Conductivity of Scandium Oxide and a New Hopping Model for Conductivity, Phys. Rev. B., 1972, 6, 1572-1580.
- S.R. Elliott, Temperature dependence of a.c. conductivity of chalcogenide glasses, Philos. Mag. B., 1978, 37, 553-560.
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