Vibrational study and thermal behavior of dihydrogenotriphosphate trihydrate of 4-aminobenzoic acid and its anhydrous new form fertilizer type NP

Authors

  • Mustapha Belhabra Laboratoire de Chimie Physique des Matériaux LCPM, Faculté des Sciences Ben M'Sik, B.P. 7955
  • Ismail Fahim Laboratoire de Chimie Physique des Matériaux LCPM, Faculté des Sciences Ben M'Sik, B.P. 7955
  • Azzedine Atibi Laboratoire de Chimie Physique des Matériaux LCPM, Faculté des Sciences Ben M'Sik, B.P. 7955
  • Khadija El Kababi Laboratoire de Chimie Physique des Matériaux LCPM, Faculté des Sciences Ben M'Sik, B.P. 7955
  • Ali Ouasri Centre Régional des métiers d'education et de formation Rabat. Maroc
  • Soufiane Zerraf Laboratoire de Chimie Physique des Matériaux LCPM, Faculté des Sciences Ben M'Sik, B.P. 7955
  • Malika Tridane Laboratoire de Chimie Physique des Matériaux LCPM, Faculté des Sciences Ben M'Sik, B.P. 7955
  • Mohammed Radid Laboratoire de Chimie Physique des Matériaux LCPM, Faculté des Sciences Ben M'Sik, B.P. 7955
  • Said Belaaouad Laboratoire de Chimie Physique des Matériaux LCPM, Faculté des Sciences Ben M'Sik, B.P. 7955

DOI:

https://doi.org/10.13171/mjc841905308mb

Abstract

Chemical synthesis methods and IR spectrometry studies are reported for an organic triphosphate (NH3C6H4COOH)3H2P3O10.3H2O and its anhydrous new form NH3C6H4COOH)3H2P3O10. The hydrate compound (NH3C6H4COOH)3H2P3O10.3H2O was synthetized by the ion-exchange resin method. The dehydration of (NH3C6H4COOH)3H2P3O10.3H2O leads at 130°C to (NH3C6H4COOH)3H2P3O10 crystallizing in the triclinic system with space group P 1 (Z = 2) [a = 14.566(6) Å, b = 6.866 (1) Å, c = 6.445 (6) Å, α = 112.36 (3) °, β = 94.51 (1) °, γ = 95.94(7) °, and V = 587.98 (1) Å3 ]. Merit’s figures are M (10) = 91.9 and F (10) = 55.6 (0.0032, 56). Its thermal behavior and kinetic study were studied by using thermal analyses TGA and DTA techniques between 25 and 600°C.

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Published

2019-05-30

Issue

Vol. 8 No. 4 (2019)

Section

Materials Chemistry

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