Telon dye removal from Cu(II)-containing aqueous media using p-diphosphonium organo-montmorillonite

Authors

  • Benamar Makhoukhi Laboratory of Separation and Purification Technology, Department of Chemistry, Tlemcen University,Box 119, Tlemcen, Algeria
  • Mohamed Amine Didi Laboratory of Separation and Purification Technology, Department of Chemistry, Tlemcen University,Box 119, Tlemcen, Algeria
  • Hidayet Moulessehoul Laboratory of Separation and Purification Technology, Department of Chemistry, Tlemcen University,Box 119, Tlemcen, Algeria
  • Abdelkrim Azzouz University of Quebec at Montreal, Department of Chemistry, Canada H3C3P8

DOI:

https://doi.org/10.13171/mjc.1.2.2011.18.10.19

Abstract

Ion-exchange of montmorillonite with para-bis(triphenyl phosphonium methylene)-benzene ions (p-TPhPMB) provided an organo-montmorillonite adsorbent with improved affinity towards Telon dyes. Adsorption tests applied to Telon-red and Telon-blue in the presence of Cu(II) cations revealed a significant increase in the maximum adsorption capacity from ca. 11-26 for the starting clay mineral to ca. 110-160 mg.g-1 after intercalation. This improvement was attributed to increases in both the organophilic character towards the organic dyestuffs investigated and the interlayers spacing. Besides dye-diphosphonium and Cu(II)-diphosphonium interactions, dye adsorption on organo-montmorillonite also involved the formation of Cu(II) exchanged Telon-dye species. It was found that dye adsorption involves not only binary interactions between the three chemical species, but also synergy due to a possible bridging action of the divalent Cu(II) cations. On organo-Mt, the organophilic character was a key factor for higher amounts of adsorbed dye.

References

- E. Assaad, A. Azzouz, D. Nistor, A. V. Ursu, T. Sajin, D. Miron, F. Monette, P. Niquette, R. Hausler, Appl. Clay Sci., 2007, 37, 258–274.

- J. Y. Bottero, K. Kathib, Water Res., 1994, 28, 483-490.

- S. A. Boyd, Environ. Sci. Technol., 1996, 9, 24-28.

- S. A. Boyd, G. Sheng, B. J. Trappen, Environ. Sci. Technol., 2001, 35, 4227-4234.

- D. C. Rodriguez- Sarmiento, J. A. Pinzon-Bello, Appl. Clay Sci., 2001, 18, 173-181.

- M. K. Sang, J. B. Dixon, Appl. Clay Sci., 2001, 18, 111-112.

- M. A. N. Lawrence, R. K. Kukkadpu, S. A. Boyd, Appl. Clay Sci., 1998, 13, 13-20.

- M. A. Didi, B. Makhoukhi, A. Azzouz, D. Villemin, Appl. Clay Sci., 2009, 42, 336-344.

- B. Makhoukhi, M. A. Didi, D. Villemin, A. Azzouz, Grasas Aceites, 2009, 60, 343-349.

- B. Makhoukhi, M. A. Didi, H., Moulessehoul, A. Azzouz, D. Villemin, Appl. Clay Sci., 2010, 50, 354-361.

- N. Al-Bastaki, F. Banat, Resour. Conserv. Recycling, 2004, 41, 103-114.

- S. A. Boyd, W. F. Jaynes, Appl. Clay Sci., 1993, 1-4, 17-30.

- A. S. Ozcan, B. Erdem, J. Hazard. Mater., 2005, 135, 141-148.

- A. S. Ozcan, J. Hazard. Mater., 2006, 142, 165-174.

- Y. H. Shen, Chemosphere, 2001, 44, 989–995.

- G. Sheng, S. Xu, S. A. Boyd, Water Res., 1996, 30, 1483–1489.

- M. Wieczorek, A. Krysztafkiewicz, T. Jesionowski, J. Phys. Chem. Solids, 2004, 65, 447–452.

- M. Arroyo, M. Suarez, M. Lopez-Manchado, J. Fernandez, J. Nanosci. Nanotechnol., 2006, 6, 2151–2154.

- A. Hartwig, D. Putz, M. Schartel, M. Wendschuh-Josties, Macromol. Chem. Phys., 2003, 204, 2247–2257.

- W. Xie, R. Xie, W. Pan, D. Hunter, B. Koene, Chem. Mater., 2002, 14, 4837–4845.

-International Union of Pure and Applied Chemistry (IUPAC), 1997. Compendium of Chemical Terminology, 2nd ed. Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford, 1997.

- R. D. Lillie, P. Pizzolato, P. T. Donaldson, Histochemistry. 1976, 49, 23-35.

-T. Bechtold, R. Mussak, Handbook of Natural Colorants. John Wiley and Son, Chichester (UK), 2009, pp.337.

- B. Tabak, S. F. Afsin, H. Icbudak, J. Therm. Anal. Calorim., 2005, 81, 311–314.

- J. Y. Yoo, J. Choi, T. Leer, J.W. Park, Water Air Soil Poll., 2003, 154, 225-237.

- M. Crocker, R. M. Herold, J. Mol. Catal., 1991, 70, 209-216.

- R. Margalef, P. Salagre, E. Fernandez, C. Claver, Catal. Lett., 1999, 60, 121–123.

- J. W. Park, P. Jaffe, Environ. Sci. Technol., 1993, 27, 2559–2565.

- R. Gullick, W. Weber, Environ. Sci. Technol., 2001, 35, 1523–1530.

- B. Makhoukhi, M. A. Didi, D. Villemin, Mater. Lett., 2008, 62, 2493–2496.

-A. Azzouz, Interactions Chitosane – particules colloidales: Synergie avec les argiles. Chapter 12. In:Crini, G., Badot, P. M., Guibal, E. (Eds). Chitine et Chitosane – Du biopolymère à l’application: Presses Universitaire de Franche-Comté, Université de Franche-Comté, Besançon, France, 2009, pp. 231-255.

- A. Azzouz, Chitosan and derivatives– behavior in dispersed state and applications. In: Davis, S. P. (Ed). Chitosan: Manufacture, Properties, and Usage. Series: Biotechnology in Agriculture, Industry and Medicine, Publisher: Nova-Publishers, New-York, USA, 2010, 4th quarter.

https://www.novapublishers.com/catalog /product_info.php?products_id=12712.

- Y. S. Ho, D. A. J. Wase, C. F. Forster, Environ. Technol., 1996, 17, 71-77.

- A. S. Özcan, A. Özcan, J. Colloid Interf. Sci., 2004, 276, 39–46.35 - A. K. Bajpai, L. Rai, Indian J. Chem. Techn., 2010, 17, 17-27.

- N. Kannan, M. M. Sundaram, Dyes Pigments, 2001, 51, 25-40.

- W. J. Weber, J. C. Morris, J. Sanitary Eng. Div. Am. Soc. Civil Eng., 1963, 89, 31–39.

- A. Mastalir, Z. Kiraly, G. Szollosi, M. Bartoky, J. Catal., 2000, 194, 146–152.

- H. A. Patel, R. S. Somani, H. C. Bajaj, R.V. Jasra, Curr. Sci. India, 2007, 92, 1004–1009.

- J. Baham, G. Sposito, J. Environ. Qua., 1994, 23, 147–153.

-G. Grigoropoulou, P. Stathi, M. A. Karakassides, M. Louloudi, Y. Eligiannakis, Colloid Surface A, 2008, 320, 25-35.

- S. J. Anderson, G. Sposito, Soil Sci. Soc. Am. J., 1991, 55,1569–1576.

-R. A. Schoonheydt, C. T. Johnston, Surface and Interface Chemistry of Clay Minerals, in: Bergaya, F., Lagaly, B. K. J., G. (Eds), Handbook of Clay Science – I. Developments in Clay Science. Elsevier, Amsterdam, 2006, pp. 87-113.

- M. B. McBride, Environmental Chemistry of Soils, Second Ed., Oxford University Press, 1994, pp. 352.

-A. Azzouz, D. Messad, D. Nistor, C. Catrinescu, A. Zvolinschi, S. Asaftei, Appl. Catal. A-Gen., 2003, 241, 1-13.

-A. Azzouz, D. Nistor, D. Miron, A. V. Ursu, T. Sajin, F. Monette, P. Niquette, R. Hausler, Thermochim. Acta, 2006, 449, 27-34.

Downloads

Published

2011-10-18

Issue

Vol. 1 No. 2 (2011)

Section

Environmental Chemistry

License

Authors who publish with this journal agree to the following terms:

    1. Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal
    2. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal
    3. Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).