Calcite, the main corrosion inhibitor contained in the raw clay (Rhassoul) of brass in 3% NaCl medium.

Authors

  • Nordin Ben Seddik Abdelmalek Essaadi University, Faculty of sciences, Tetouan
  • Ihssane Raissouni Abdelmalek Essaadi University, Faculty of sciences, Tetouan
  • Khalid Draoui Abdelmalek Essaadi University, Faculty of sciences, Tetouan
  • Ahmed Ait Aghzzaf Abdelmalek Essaadi University, École Normale Supérieure, Tetouan
  • Anas Chraka Abdelmalek Essaadi University, Faculty of sciences, Tetouan
  • Badr Aznag REMINEX-Groupe, MANAGEM, Marrakech
  • Faiza Chaouket Abdelmalek Essaadi University, Faculty of sciences, Tetouan
  • Dounia Bouchta Abdelmalek Essaadi University, Faculty of sciences, Tetouan

DOI:

https://doi.org/10.13171/mjc93191016530nbs

Abstract

Corrosion control of copper alloys such as brass is of great interest to researchers and scientists. Clays become materials of choice as corrosion inhibitors and as their reservoir in corrosive environments. The effect of Rhassoul on the corrosion of Cu-36Zn alloy in 3% NaCl solution has been studied. Electrochemical techniques showed that the optimum concentration was 1g/L showing the highest inhibition efficiency (82%). This concentration was evaluated at five different temperatures. In order to determine the influence of purification, this result was compared to that of the homoionic clay labeled Na+-ST and to the pure calcite. Chemical composition of the brass specimen and solutions were done by inductively coupled plasma atomic emission spectrometry (ICP-AES) and atomic absorption (AA) respectively. The effectiveness of this clay against the dissolution of Zinc reached 61%. XRD technique demonstrated the homoionization of this clay by shifting the basal spacing d001.

Author Biographies

Nordin Ben Seddik, Abdelmalek Essaadi University, Faculty of sciences, Tetouan

Department of chemistry, Materials and interfacial systems, Laboratory,

Ihssane Raissouni, Abdelmalek Essaadi University, Faculty of sciences, Tetouan

Department of chemistry, Materials and interfacial systems, Laboratory

Khalid Draoui, Abdelmalek Essaadi University, Faculty of sciences, Tetouan

Department of chemistry, Materials and interfacial systems, Laboratory

Ahmed Ait Aghzzaf, Abdelmalek Essaadi University, École Normale Supérieure, Tetouan

Department of chemistry, Laboratory of Applied and Didactic Sciences (LAADS)

Anas Chraka, Abdelmalek Essaadi University, Faculty of sciences, Tetouan

Department of chemistry, Materials and interfacial systems, Laboratory

Badr Aznag, REMINEX-Groupe, MANAGEM, Marrakech

Research Center

Faiza Chaouket, Abdelmalek Essaadi University, Faculty of sciences, Tetouan

Department of chemistry, Materials and interfacial systems, Laboratory

Dounia Bouchta, Abdelmalek Essaadi University, Faculty of sciences, Tetouan

Department of chemistry, Materials and interfacial systems, Laboratory

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Published

2019-10-16

Issue

Vol. 9 No. 3 (2019)

Section

Electrochemistry

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