Synthesis, Structural, Viscosimetric, And Rheological Study, of A New Trifunctional Phosphorus Epoxyde Prepolymer , Tri-Glycidyl Ether Tri-Mercaptoethanol Of Phosphore (TGETMEP)

Authors

  • Atiqa Bekhta Laboratory of Agro-resource, Polymer and Process Engineering (LAPPE) Team of Organic and Polymer Chemistry (TOPC), Faculty of Science, University Ibn Tofail, BP133, 14000, Kenitra,
  • Rachid Hsissou Laboratory of Agro-resource, Polymer and Process Engineering (LAPPE) Team of Organic and Polymer Chemistry (TOPC), Faculty of Science, University Ibn Tofail, BP133, 14000, Kenitra,
  • Mehdi El Bouchiti Laboratory of Agro-resource, Polymer and Process Engineering (LAPPE) Team of Organic and Polymer Chemistry (TOPC), Faculty of Science, University Ibn Tofail, BP133, 14000, Kenitra,
  • Ahmed EL Harfi Laboratory of Agro-resource, Polymer and Process Engineering (LAPPE) Team of Organic and Polymer Chemistry (TOPC), Faculty of Science, University Ibn Tofail, BP133, 14000, Kenitra,

DOI:

https://doi.org/10.13171/mjc61/01610151105/bekhta

Abstract

The aim of our work is to synthesize a new phosphorus tri-functional epoxy resin tri-glycidyl ether tri-mercaptoethanol of phosphorus (TGETMEP) in two stages. In the first stage, we got the precursor molecule of the epoxy matrix tri-mercaptoethanol phosphate (METR). The second step led us to the synthesis of tri-functional resin TMEP condensation with epichlorohydrin. The standard TGETMEP resin was characterized by the Fourier infrared transformation (FTIR) and nuclear magnetic resonance (NMR), on one hand. The viscosimetric analysis was investigated by the Hebbelod capillary viscometer and rheometer Rheomat 01, on the other hand. The cross-linked resins and tertiary formulated composites have been studied by the rheometer 01 which was observed by means of SEM.

References

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Published

2016-10-15

Issue

Vol. 6 No. 1 (2016)

Section

Polymer Chemistry

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